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The sulfonation of an aromatic ring with SO_3 and H_2SO_4 is reversible. That is, heating benzenesulfonic acid with H_2SO_4 yields benzene. Show the mechanism of the desulfonation reaction. What is the electrophile?
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Experimental and molecular modelling studies on aromatic sulfonation - Journal of the Chemical Society, Perkin Transactions 2 (RSC Publishing) DOI:10.1039/B109338J
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Sulfonation mechanism of benzene with SO3 in sulfuric acid or oleum or aprotic solvent: Obeying the transition state theory via a trimolecular electrophilic substitution clarified by density functional theory calculation - ScienceDirect
Benzene Reactions - Sulphonation Of Benzene, Nitration Of Nitrobenzene & Halogenation Of Benzene
Nitration and Sulfonation Reactions In Electrophilic Aromatic Substitution